Interaction between a dimethylamino group and an electron-deficient alkene in ethyl (E)-2-cyano-3-(8-dimethylamino-1-naphthyl)propenoate

BELL, P.C., DRAMEH, M., HANLY, N. and WALLIS, J.D., 2000. Interaction between a dimethylamino group and an electron-deficient alkene in ethyl (E)-2-cyano-3-(8-dimethylamino-1-naphthyl)propenoate. Acta Crystallographica Section C-Crystal Structure Communications, 56, pp. 670-671. ISSN 0108-2701

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Abstract

The interaction between the peri substituents in the title compound, C18H18N2O2, measured at 150 K, represents an early stage in the addition reaction of an amino group to an electron-deficient alkene, and has an N...Csp2 separation of 2.531 (2) Å; comparison with related structures indicates that the nitrile group activates an alkene to nucleophilic attack more than a coplanar carboxylic ester group.

Item Type: Journal article
Publication Title: Acta Crystallographica Section C-Crystal Structure Communications
Creators: Bell, P.C., Drameh, M., Hanly, N. and Wallis, J.D.
Publisher: International Union of Crystallography
Date: 2000
Volume: 56
ISSN: 0108-2701
Identifiers:
NumberType
10.1107/S0108270100000512DOI
Divisions: Schools > School of Science and Technology
Depositing User: EPrints Services
Date Added: 09 Oct 2015 10:29
Last Modified: 23 Aug 2016 09:10
URI: http://irep.ntu.ac.uk/id/eprint/13686

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