New chiral organosulfur donors related to bis(ethylenedithio)tetrathiafulvalene

YANG, S., BROOKS, A.C., MARTIN, L., DAY, P., PILKINGTON, M., CLEGG, W., HARRINGTON, R.W., RUSSO, L. and WALLIS, J.D., 2010. New chiral organosulfur donors related to bis(ethylenedithio)tetrathiafulvalene. Tetrahedron, 66 (34), pp. 6977-6989. ISSN 0040-4020

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Abstract

Six new enantiopure chiral organosulfur donors, with structures related to BEDT-TTF, have been synthesised for use in the preparation of organic metals, starting either by double nucleophilic substitutions on the bis-mesylate of 2R,4Rpentane-2,4-diol or by a cycloaddition with subsequent elimination of acetic acid on the enol acetate of (+)-nopinone. Crystal structures of some of their radical cation triiodides salts and TCNQ complexes are reported.

Item Type: Journal article
Publication Title: Tetrahedron
Creators: Yang, S., Brooks, A.C., Martin, L., Day, P., Pilkington, M., Clegg, W., Harrington, R.W., Russo, L. and Wallis, J.D.
Publisher: Elsevier (not including Cell Press)
Date: 18 June 2010
Volume: 66
Number: 34
ISSN: 0040-4020
Identifiers:
NumberType
10.1016/j.tet.2010.06.034DOI
Rights: Copyright © 2010 Elsevier B.V.
Divisions: Schools > School of Science and Technology
Depositing User: EPrints Services
Date Added: 09 Oct 2015 10:31
Last Modified: 09 Jun 2017 13:31
URI: http://irep.ntu.ac.uk/id/eprint/14121

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