New chiral organosulfur donors related to bis(ethylenedithio)tetrathiafulvalene

Yang, S, Brooks, AC, Martin, L ORCID: 0000-0002-5330-5700, Day, P, Pilkington, M, Clegg, W, Harrington, RW, Russo, L and Wallis, JD ORCID: 0000-0001-7259-8783, 2010. New chiral organosulfur donors related to bis(ethylenedithio)tetrathiafulvalene. Tetrahedron, 66 (34), pp. 6977-6989. ISSN 0040-4020

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Abstract

Six new enantiopure chiral organosulfur donors, with structures related to BEDT-TTF, have been synthesised for use in the preparation of organic metals, starting either by double nucleophilic substitutions on the bis-mesylate of 2R,4Rpentane-2,4-diol or by a cycloaddition with subsequent elimination of acetic acid on the enol acetate of (+)-nopinone. Crystal structures of some of their radical cation triiodides salts and TCNQ complexes are reported.

Item Type: Journal article
Publication Title: Tetrahedron
Creators: Yang, S., Brooks, A.C., Martin, L., Day, P., Pilkington, M., Clegg, W., Harrington, R.W., Russo, L. and Wallis, J.D.
Publisher: Elsevier (not including Cell Press)
Date: 18 June 2010
Volume: 66
Number: 34
ISSN: 0040-4020
Identifiers:
NumberType
10.1016/j.tet.2010.06.034DOI
Rights: Copyright © 2010 Elsevier B.V.
Divisions: Schools > School of Science and Technology
Depositing User: EPrints Services
Date Added: 09 Oct 2015 10:31
Last Modified: 09 Jun 2017 13:31
URI: http://irep.ntu.ac.uk/id/eprint/14121

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