Synthetic strategies for preparing BEDT-TTF derivatives functionalised with metal ion binding groups

Wang, Q, Day, P, Griffiths, JP, Nie, H and Wallis, JD ORCID: 0000-0001-7259-8783, 2006. Synthetic strategies for preparing BEDT-TTF derivatives functionalised with metal ion binding groups. New Journal of Chemistry, 30 (12), pp. 1790-1800. ISSN 1369-9261

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Abstract

The syntheses of BEDT-TTF (ET) derivatives with potential metal ion binding pyridyl, bipyridyl and terpyridyl groups are achieved either by stepwise construction of the organosulfur core or via reactions of hydroxymethyl-ET for which a cheap and efficient four step route is reported. The tosylate of hydroxymethyl-ET, reported for the first time, undergoes nucleophilic substitutions with pyridyl, bipyridyl- and terpyridyl-thiolates to give new donors. The X-ray crystal structures of two substituted ET derivatives show considerable deviation of the organosulfur donor system from planarity by bending about the short molecular axis of the ET group.

Item Type: Journal article
Publication Title: New Journal of Chemistry
Creators: Wang, Q., Day, P., Griffiths, J.P., Nie, H. and Wallis, J.D.
Publisher: Royal Society of Chemistry
Date: 2006
Volume: 30
Number: 12
ISSN: 1369-9261
Identifiers:
NumberType
10.1039/b606715hDOI
Rights: © Royal Society of Chemistry
Divisions: Schools > School of Science and Technology
Depositing User: EPrints Services
Date Added: 09 Oct 2015 11:10
Last Modified: 09 Jun 2017 13:51
URI: http://irep.ntu.ac.uk/id/eprint/23827

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