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Saritemur, G., Nomen Miralles, L., Husson, D., Pitak, M.B., Coles, S.J. and Wallis, J.D. 
ORCID: 0000-0001-7259-8783,
2016.
Two modes of peri-interaction between an aldehyde group and a carboxylate anion in naphthalaldehydate salts.
CrystEngComm, 18 (6), pp. 948-961.
ISSN 1466-8033
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Abstract
Crystal structures of the salts of 1,8-naphthalaldehydic acid (8-formyl-1-naphthoic acid) show one of two types of interaction between the functional groups. In the more commonly observed case, a carboxylate oxygen lies close to the aldehyde carbonyl carbon atom (O⋯C: 2.445–2.630 Å) and makes an n–pi* interaction. However, in two other cases the carboxylate group has rotated so that the aldehyde now directs its hydrogen atom at the face of the carboxylate group and forms a surprisingly short contact with the carbon atom (H⋯C: 2.29 and 2.42 Å). This interaction is likely to be electrostatic in nature.
| Item Type: | Journal article | ||||
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| Publication Title: | CrystEngComm | ||||
| Creators: | Saritemur, G., Nomen Miralles, L., Husson, D., Pitak, M.B., Coles, S.J. and Wallis, J.D. | ||||
| Publisher: | Royal Society of Chemistry | ||||
| Date: | 2016 | ||||
| Volume: | 18 | ||||
| Number: | 6 | ||||
| ISSN: | 1466-8033 | ||||
| Identifiers: |
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| Rights: | Open access article licensed under a Creative Commons Attribution 3.0 Unported Licence. © The Royal Society of Chemistry. | ||||
| Divisions: | Schools > School of Science and Technology | ||||
| Record created by: | Jill Tomkinson | ||||
| Date Added: | 08 Mar 2016 10:48 | ||||
| Last Modified: | 09 Jun 2017 13:59 | ||||
| Related URLs: | |||||
| URI: | https://irep.ntu.ac.uk/id/eprint/27095 |
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