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Wang, Q., Martin, L. 
ORCID: 0000-0002-5330-5700, Blake, A.J., Day, P., Akutsu, H. and Wallis, J.D. ORCID: 0000-0001-7259-8783,
2016.
Coordination chemistry of 2,2′-bipyridyl- and 2,2′:6′,2″-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2′-bipyridine-4-thiomethyl-BEDT-TTF.
Inorganic Chemistry, 55 (17), pp. 8543-8551.
ISSN 0020-1669
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Abstract
Molecules of tris(2,2’-bipyridine-4-thiomethyl-BEDT-TTF)iron(II) (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) assemble in pairs to form a novel supramolecular capsular structure in the solid state. Three BEDT-TTF residues from one complex lie in the three grooves between coordinated bipyridines of the other complex, and vice versa, to form a capsule with three-fold rotational symmetry and an internal volume of ca. 160 Å3. Further aspects of the coordination chemistry of this ligand, its 6-substituted isomer and the 2,2’:6’2’’- terpyridyl-4’-thiomethyl-BEDT-TTF analogue are described.
| Item Type: | Journal article | ||||
|---|---|---|---|---|---|
| Publication Title: | Inorganic Chemistry | ||||
| Creators: | Wang, Q., Martin, L., Blake, A.J., Day, P., Akutsu, H. and Wallis, J.D. | ||||
| Publisher: | American Chemical Society | ||||
| Date: | 2016 | ||||
| Volume: | 55 | ||||
| Number: | 17 | ||||
| ISSN: | 0020-1669 | ||||
| Identifiers: |
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| Divisions: | Schools > School of Science and Technology | ||||
| Record created by: | Jonathan Gallacher | ||||
| Date Added: | 07 Oct 2016 08:22 | ||||
| Last Modified: | 12 Oct 2017 08:54 | ||||
| URI: | https://irep.ntu.ac.uk/id/eprint/28805 |
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