Wang, Q., Day, P., Griffiths, J.P., Nie, H. and Wallis, J.D. ORCID: 0000-0001-7259-8783,
2006.
Synthetic strategies for preparing BEDT-TTF derivatives functionalised with metal ion binding groups.
New Journal of Chemistry, 30 (12), pp. 1790-1800.
ISSN 1369-9261
Abstract
The syntheses of BEDT-TTF (ET) derivatives with potential metal ion binding pyridyl, bipyridyl and terpyridyl groups are achieved either by stepwise construction of the organosulfur core or via reactions of hydroxymethyl-ET for which a cheap and efficient four step route is reported. The tosylate of hydroxymethyl-ET, reported for the first time, undergoes nucleophilic substitutions with pyridyl, bipyridyl- and terpyridyl-thiolates to give new donors. The X-ray crystal structures of two substituted ET derivatives show considerable deviation of the organosulfur donor system from planarity by bending about the short molecular axis of the ET group.
Item Type: | Journal article | ||||
---|---|---|---|---|---|
Publication Title: | New Journal of Chemistry | ||||
Creators: | Wang, Q., Day, P., Griffiths, J.P., Nie, H. and Wallis, J.D. | ||||
Publisher: | Royal Society of Chemistry | ||||
Date: | 2006 | ||||
Volume: | 30 | ||||
Number: | 12 | ||||
ISSN: | 1369-9261 | ||||
Identifiers: |
|
||||
Rights: | © Royal Society of Chemistry | ||||
Divisions: | Schools > School of Science and Technology | ||||
Record created by: | EPrints Services | ||||
Date Added: | 09 Oct 2015 09:47 | ||||
Last Modified: | 09 Jun 2017 13:11 | ||||
URI: | https://irep.ntu.ac.uk/id/eprint/2906 |
Actions (login required)
![]() |
Edit View |
Views
Views per month over past year
Downloads
Downloads per month over past year