WANG, Q., DAY, P., GRIFFITHS, J.P., NIE, H. and WALLIS, J.D., 2006. Synthetic strategies for preparing BEDT-TTF derivatives functionalised with metal ion binding groups. New Journal of Chemistry, 30 (12), pp. 1790-1800. ISSN 1369-9261Full text not available from this repository.
The syntheses of BEDT-TTF (ET) derivatives with potential metal ion binding pyridyl, bipyridyl and terpyridyl groups are achieved either by stepwise construction of the organosulfur core or via reactions of hydroxymethyl-ET for which a cheap and efficient four step route is reported. The tosylate of hydroxymethyl-ET, reported for the first time, undergoes nucleophilic substitutions with pyridyl, bipyridyl- and terpyridyl-thiolates to give new donors. The X-ray crystal structures of two substituted ET derivatives show considerable deviation of the organosulfur donor system from planarity by bending about the short molecular axis of the ET group.
|Item Type:||Journal article|
|Publication Title:||New Journal of Chemistry|
|Creators:||Wang, Q., Day, P., Griffiths, J.P., Nie, H. and Wallis, J.D.|
|Publisher:||Royal Society of Chemistry|
|Rights:||© Royal Society of Chemistry|
|Divisions:||Schools > School of Science and Technology|
|Depositing User:||EPrints Services|
|Date Added:||09 Oct 2015 09:47|
|Last Modified:||23 Aug 2016 09:06|
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