Triazine functionalized porous covalent organic framework for photo-organocatalytic E–Z isomerization of olefins

Bhadra, M., Kandambeth, S., Sahoo, M.K., Addicoat, M. ORCID: 0000-0002-5406-7927, Balaraman, E. and Banerjee, R., 2019. Triazine functionalized porous covalent organic framework for photo-organocatalytic E–Z isomerization of olefins. Journal of the American Chemical Society. ISSN 0002-7863

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Abstract

Visible light-mediated photocatalytic organic transformation has drawn significant attention as an alternative process for replacing thermal reactions. Although precious metal/organic dyes based homogeneous photocatalysts have been developed, their toxic and nonreusable nature makes them inappropriate for large-scale production. Therefore, we have synthesized a triazine and a keto functionalized nonmetal based covalent organic framework (TpTt) for heterogeneous photocatalysis. As the catalyst shows significant absorption of visible light, it has been applied for the photocatalytic uphill conversion of trans-stilbene to cis-stilbene in the presence of blue light-emitting diodes with broad substrate scope via an energy transfer process.

Item Type: Journal article
Publication Title: Journal of the American Chemical Society
Creators: Bhadra, M., Kandambeth, S., Sahoo, M.K., Addicoat, M., Balaraman, E. and Banerjee, R.
Publisher: American Chemical Society
Date: 4 April 2019
ISSN: 0002-7863
Identifiers:
NumberType
10.1021/jacs.9b01891DOI
Divisions: Schools > School of Science and Technology
Depositing User: Jonathan Gallacher
Date Added: 15 Apr 2019 08:14
Last Modified: 15 Apr 2019 08:14
URI: http://irep.ntu.ac.uk/id/eprint/36248

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