Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase

Mekapothula, S., Addicoat, M.A. ORCID: 0000-0002-5406-7927, Boocock, D.J. ORCID: 0000-0002-7333-3549, Wallis, J.D., Cragg, P.J. and Cave, G.W.V. ORCID: 0000-0002-4167-1332, 2020. Silica bound co-pillar[4+1]arene as a novel supramolecular stationary phase. Chemical Communications. ISSN 1359-7345

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Abstract

A novel co-pillar[4+1]arene incorporating two bromo-octyl substituents has been synthesised for the first time, using microwave irradiation in high yield (88%) in under four minutes, and bound to the surface of chromatographic silica particles. The resulting new stationary phase has been successfully utilised to separate xylene isomers via liquid chromatographic techniques.

Item Type: Journal article
Publication Title: Chemical Communications
Creators: Mekapothula, S., Addicoat, M.A., Boocock, D.J., Wallis, J.D., Cragg, P.J. and Cave, G.W.V.
Publisher: Royal Society of Chemistry
Date: 8 January 2020
ISSN: 1359-7345
Identifiers:
NumberType
10.1039/c9cc09656fDOI
1276448Other
Record created by: Jonathan Gallacher
Date Added: 23 Jan 2020 13:17
Last Modified: 30 Sep 2020 10:41
URI: http://irep.ntu.ac.uk/id/eprint/39053

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