Electrochemical dehydrogenative C(sp2)−H amination

Puthanveedu, M., Khamraev, V., Brieger, L., Strohmann, C. and Antonchick, A.P. ORCID: 0000-0003-0435-9443, 2021. Electrochemical dehydrogenative C(sp2)−H amination. Chemistry – A European Journal, 27 (30), pp. 8008-8012. ISSN 0947-6539

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Abstract

A transition-metal-free direct electrolytic C−H amination involving an electrochemically generated nitrenium ion intermediate has been developed. The electrosynthesis takes place in the absence of any organoiodine catalysts and is enabled by an in situ generated electrolyte. A novel, efficient intramolecular and intermolecular C−H amination has been demonstrated using a simple reaction setup.

Item Type: Journal article
Publication Title: Chemistry – A European Journal
Creators: Puthanveedu, M., Khamraev, V., Brieger, L., Strohmann, C. and Antonchick, A.P.
Publisher: Wiley
Date: 26 May 2021
Volume: 27
Number: 30
ISSN: 0947-6539
Identifiers:
NumberType
10.1002/chem.202100960DOI
1447775Other
Rights: © 2021 The Authors. Published by Wiley-V. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
Divisions: Schools > School of Science and Technology
Record created by: Linda Sullivan
Date Added: 01 Jul 2021 07:38
Last Modified: 01 Jul 2021 07:38
URI: http://irep.ntu.ac.uk/id/eprint/43280

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