Probing the reactivity of a 2,2′-bipyridyl-3,3′-bis-imine ligand by X-ray crystallography

Wang, J., Hayward, J.J., Gumbau-Brisa, R., Wallis, J.D. ORCID: 0000-0001-7259-8783, Stoeckli-Evans, H. and Pilkington, M., 2015. Probing the reactivity of a 2,2′-bipyridyl-3,3′-bis-imine ligand by X-ray crystallography. CrystEngComm, 17 (5), pp. 1159-1167. ISSN 1466-8033

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Abstract

The reactivity of a Schiff-base bis-imine ligand 3 is probed by X-ray diffraction studies. Its susceptibility to hydrolysis, oxidation and nucleophilic addition reactions is demonstrated by the isolation of the methanol adduct 4 and two diazapene heterocycles 5 and 6. This reactivity is also reflected in the molecular structures of two coordination complexes isolated by the reaction of 3 with MIJhfac)2 salts, to afford [Cu(5)-(hfac)(tfa)] (8) and [Zn(6)(hfac)2] (9).

Item Type:	Journal article
Publication Title:	CrystEngComm
Creators:	Wang, J., Hayward, J.J., Gumbau-Brisa, R., Wallis, J.D., Stoeckli-Evans, H. and Pilkington, M.
Publisher:	Royal Society of Chemistry
Place of Publication:	Cambridge
Date:	2015
Volume:	17
Number:	5
ISSN:	1466-8033
Identifiers:	Number Type 10.1039/C4CE01952K DOI
Rights:	© Royal Society of Chemistry 2015
Divisions:	Schools > School of Science and Technology
Record created by:	EPrints Services
Date Added:	09 Oct 2015 10:05
Last Modified:	09 Jun 2017 13:18
URI:	https://irep.ntu.ac.uk/id/eprint/7496

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