New semiconducting radical-cation salts of chiral bis(2-hydroxylpropylthio)ethylenedithio TTF

Lopez, J.R., Martin, L. ORCID: 0000-0002-5330-5700, Wallis, J.D., Akutsu, H., Yamada, J., Nakatsuji, S., Wilson, C., Christensen, J. and Coles, S.J., 2017. New semiconducting radical-cation salts of chiral bis(2-hydroxylpropylthio)ethylenedithio TTF. CrystEngComm, 19 (32), pp. 4848-4856. ISSN 1466-8033

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Abstract

Electrocrystallisations of the chiral donor molecule S,S-bis(2-hydroxylpropylthio)ethylenedithiotetrathiafulvalene have produced a series of 1 : 1 semiconducting radical-cation salts with anions bromide, chloride, perchlorate and hexafluorophosphate. The flexibility and hydrogen bonding ability of the donor's chiral side chains lead to three quite different packing arrangements of donor cation pairs. Conductivity is maintained despite significant separations of donor cation pairs in some cases.

Item Type:	Journal article
Publication Title:	CrystEngComm
Creators:	Lopez, J.R., Martin, L., Wallis, J.D., Akutsu, H., Yamada, J., Nakatsuji, S., Wilson, C., Christensen, J. and Coles, S.J.
Publisher:	Royal Society of Chemistry
Date:	2 August 2017
Volume:	19
Number:	32
ISSN:	1466-8033
Identifiers:	Number Type 10.1039/C7CE01014A DOI
Divisions:	Schools > School of Science and Technology
Record created by:	Jonathan Gallacher
Date Added:	14 Aug 2017 13:50
Last Modified:	03 Aug 2018 03:00
URI:	https://irep.ntu.ac.uk/id/eprint/31413

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