Short, J., Blundell, T.J., Yang, S., Sahin, O., Shakespeare, Y., Smith, E.L. ORCID: 0000-0001-5844-0883, Wallis, J.D. ORCID: 0000-0001-7259-8783 and Martin, L. ORCID: 0000-0002-5330-5700, 2020. Synthesis and structures of polyiodide radical cation salts of donors combining tetrathiafulvalene with multiple thiophene or oligo-thiophene substituents. CrystEngComm.
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Abstract
A series of TTF and EDT-TTF derived donors bearing thiophene, bithiophene and terthiophene side chains is described, from which a group of six radical cation salts with polyiodide ions were formed and structurally characterised. Typically, they contain complex networks of pentaiodide or triiodide anions or both, in some cases including further iodine, with networks of eight, ten, twelve or sixteen iodine atoms. Donor monocations form face-to-face pairs, but tetrakis-substituted donors are slipped along their main axis so the donor side chains can wrap around each other.
Item Type: | Journal article | ||||||
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Publication Title: | CrystEngComm | ||||||
Creators: | Short, J., Blundell, T.J., Yang, S., Sahin, O., Shakespeare, Y., Smith, E.L., Wallis, J.D. and Martin, L. | ||||||
Publisher: | Royal Society of Chemistry (RSC) | ||||||
Date: | 16 September 2020 | ||||||
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Rights: | This journal is © The Royal Society of Chemistry 2020. Open Access Article. Published on 16 September 2020. Downloaded on 9/21/2020 11:24:31 AM. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | ||||||
Divisions: | Schools > School of Science and Technology | ||||||
Record created by: | Linda Sullivan | ||||||
Date Added: | 23 Sep 2020 14:23 | ||||||
Last Modified: | 31 May 2021 15:16 | ||||||
URI: | https://irep.ntu.ac.uk/id/eprint/40898 |
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