An octahedral tetrachlorido Fe(II) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures

Rusbridge, E.K., Peng, Y., Powell, A.K., Robinson, D. ORCID: 0000-0003-2760-7163 and Fitzpatrick, A.J. ORCID: 0000-0001-9436-8129, 2018. An octahedral tetrachlorido Fe(II) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures. Dalton Transactions. ISSN 1477-9226

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Abstract

An air stable, neutral Fe(II) complex with four equatorial chlorido ligands has been stabilised through a serendipitous redox process and in situ ligand protonation. A three dimensional non-covalent network composed of halogen bonding and π-π stacking propagates magnetic exchange interactions though the lattice. The electronic structure has been investigated using DFT.

Item Type: Journal article
Publication Title: Dalton Transactions
Creators: Rusbridge, E.K., Peng, Y., Powell, A.K., Robinson, D. and Fitzpatrick, A.J.
Publisher: Royal Society of Chemistry
Date: 11 May 2018
ISSN: 1477-9226
Identifiers:
NumberType
10.1039/C8DT01401ADOI
Divisions: Schools > School of Science and Technology
Depositing User: Jonathan Gallacher
Date Added: 11 May 2018 15:06
Last Modified: 11 May 2018 15:06
URI: http://irep.ntu.ac.uk/id/eprint/33546

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