An octahedral tetrachlorido Fe(II) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures

Rusbridge, EK ORCID: https://orcid.org/0000-0001-8470-1039, Peng, Y, Powell, AK, Robinson, D ORCID: https://orcid.org/0000-0003-2760-7163 and Fitzpatrick, AJ ORCID: https://orcid.org/0000-0001-9436-8129, 2018. An octahedral tetrachlorido Fe(II) complex with aminopyrazinium ligands from a serendipitous redox synthesis exhibiting magnetic exchange through non-covalent 3-D architectures. Dalton Transactions. ISSN 1477-9226

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Abstract

An air stable, neutral Fe(II) complex with four equatorial chlorido ligands has been stabilised through a serendipitous redox process and in situ ligand protonation. A three dimensional non-covalent network composed of halogen bonding and π-π stacking propagates magnetic exchange interactions though the lattice. The electronic structure has been investigated using DFT.

Item Type:	Journal article
Publication Title:	Dalton Transactions
Creators:	Rusbridge, E.K., Peng, Y., Powell, A.K., Robinson, D. and Fitzpatrick, A.J.
Publisher:	Royal Society of Chemistry
Date:	11 May 2018
ISSN:	1477-9226
Identifiers:	Number Type 10.1039/C8DT01401A DOI
Divisions:	Schools > School of Science and Technology
Record created by:	Jonathan Gallacher
Date Added:	11 May 2018 15:06
Last Modified:	01 Feb 2022 15:43
URI:	https://irep.ntu.ac.uk/id/eprint/33546

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