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Antonchick, A.P. 
ORCID: 0000-0003-0435-9443, Waldmann, H., Shaaban, S., Li, H. and Merten, C.,
2021.
Rhodium(III)-catalyzed enantioselective benzamidation of cyclopropenes.
Synthesis, 53 (13), pp. 2192-2200.
ISSN 0039-7881
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Abstract
Cyclopropylamines are characteristic structural motifs found in a variety of natural products and pharmaceuticals and therefore engaging targets for the development of new methods for their synthesis. Herein the synthesis of enantioenriched cyclopropylamines through catalytic enantioselective C–H functionalization using a chiral RhJasCp complex is reported. The reaction proceeds under mild conditions with high enantiocontrol. This reaction enables access to cyclopropylamines with three contiguous stereocenters originating from the corresponding cyclopropenes.
| Item Type: | Journal article | ||||||
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| Alternative Title: | Rh(III)-catalyzed enantioselective benzamidation of cyclopropenes | ||||||
| Publication Title: | Synthesis | ||||||
| Creators: | Antonchick, A.P., Waldmann, H., Shaaban, S., Li, H. and Merten, C. | ||||||
| Publisher: | Georg Thieme Verlag KG | ||||||
| Date: | July 2021 | ||||||
| Volume: | 53 | ||||||
| Number: | 13 | ||||||
| ISSN: | 0039-7881 | ||||||
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| Divisions: | Schools > School of Science and Technology | ||||||
| Record created by: | Linda Sullivan | ||||||
| Date Added: | 01 Jul 2021 08:10 | ||||||
| Last Modified: | 18 Feb 2022 03:00 | ||||||
| URI: | https://irep.ntu.ac.uk/id/eprint/43282 |
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