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Sahin, O. and Wallis, J.D. 
ORCID: 0000-0001-7259-8783,
2023.
Crystal structure of bis(mesityl)(pyrrol-1-yl)borane.
Acta Crystallographica Section E Crystallographic Communications, E79 (1), pp. 50-53.
ISSN 2056-9890
Official URL: https://doi.org/10.1107/s2056989022011768
Abstract
In the crystal structure of the title compound, C22H26BN, the B atom acts to reduce the delocalization of the nitrogen lone-pair electron density into the pyrrole ring, so that the two N—C bonds increase in length to 1.4005 (14) and 1.3981 (14) Å. The N—B bond length is 1.4425 (15) Å, which is longer than a typical N—B bond because the nitrogen lone pair is not fully available to participate in the bond.
| Item Type: | Journal article | ||||||
|---|---|---|---|---|---|---|---|
| Publication Title: | Acta Crystallographica Section E Crystallographic Communications | ||||||
| Creators: | Sahin, O. and Wallis, J.D. | ||||||
| Publisher: | International Union of Crystallography (IUCr) | ||||||
| Date: | 1 January 2023 | ||||||
| Volume: | E79 | ||||||
| Number: | 1 | ||||||
| ISSN: | 2056-9890 | ||||||
| Identifiers: |
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| Rights: | Open Access: Attribution 4.0 International (CC BY 4.0) | ||||||
| Record created by: | Jonathan Gallacher | ||||||
| Date Added: | 17 Jan 2023 09:59 | ||||||
| Last Modified: | 17 Jan 2023 09:59 | ||||||
| URI: | https://irep.ntu.ac.uk/id/eprint/47904 |
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