Crystal structure of bis(mesityl)(pyrrol-1-yl)borane

Sahin, O and Wallis, JD ORCID: https://orcid.org/0000-0001-7259-8783, 2023. Crystal structure of bis(mesityl)(pyrrol-1-yl)borane. Acta Crystallographica Section E Crystallographic Communications, E79 (1), pp. 50-53. ISSN 2056-9890

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Abstract

In the crystal structure of the title compound, C22H26BN, the B atom acts to reduce the delocalization of the nitro­gen lone-pair electron density into the pyrrole ring, so that the two N—C bonds increase in length to 1.4005 (14) and 1.3981 (14) Å. The N—B bond length is 1.4425 (15) Å, which is longer than a typical N—B bond because the nitro­gen lone pair is not fully available to participate in the bond.

Item Type:	Journal article
Publication Title:	Acta Crystallographica Section E Crystallographic Communications
Creators:	Sahin, O. and Wallis, J.D.
Publisher:	International Union of Crystallography (IUCr)
Date:	1 January 2023
Volume:	E79
Number:	1
ISSN:	2056-9890
Identifiers:	Number Type 10.1107/s2056989022011768 DOI 1634060 Other
Rights:	Open Access: Attribution 4.0 International (CC BY 4.0)
Record created by:	Jonathan Gallacher
Date Added:	17 Jan 2023 09:59
Last Modified:	17 Jan 2023 09:59
URI:	https://irep.ntu.ac.uk/id/eprint/47904

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