trans-bis{1-[2-(2,6-diisopropylanilino)phenyl]-3-isopropylimidazolin-2-ylidenyl-κc2}diiodidopalladium(ii) benzene disolvate

DALY, C.G., SINGH, K. and CROSS, W.B., 2011. trans-bis{1-[2-(2,6-diisopropylanilino)phenyl]-3-isopropylimidazolin-2-ylidenyl-κc2}diiodidopalladium(ii) benzene disolvate. Acta Crystallographica Section E: Structure Reports Online, 67 (6). ISSN 1600-5368

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Abstract

In the title complex, [PdI2(C24H31N3)2]∙2C6H6, the Pd2+ ion is located on an inversion centre in a slightly distorted square-planar geometry. The angle between the I2C2 square plane and the mean plane of the N-heterocyclic carbene ring is 79.8 (2)°, with I-Pd-C-N torsion angles of -81.1 (6) and -78.2 (5)°. The Pd-carbene and Pd-I distances are 2.016 (6) and 2.5971 (10) Å, respectively.

Item Type: Journal article
Publication Title: Acta Crystallographica Section E: Structure Reports Online
Creators: Daly, C.G., Singh, K. and Cross, W.B.
Publisher: Wiley-Blackwell
Date: 2011
Volume: 67
Number: 6
ISSN: 1600-5368
Identifiers:
NumberType
10.1107/S1600536811015431DOI
Rights: Copyright © International Union of Crystallography
Divisions: Schools > School of Science and Technology
Depositing User: EPrints Services
Date Added: 09 Oct 2015 10:10
Last Modified: 09 Jun 2017 13:21
URI: http://irep.ntu.ac.uk/id/eprint/8766

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