Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts

AWHEDA, I., KRIVICKAS, S.J., YANG, S., MARTIN, L., GUZIAK, M.A., BROOKS, A.C., PELLETIER, F., LE KERNEAU, M., DAY, P., HORTON, P.N., AKUTSU, H. and WALLIS, J.D., 2013. Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts. Tetrahedron, 69 (41), pp. 8738-8750. ISSN 0040-4020

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Abstract

The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT-TTF acetamides. Three charge transfer salts of enantiopure poly-hydroxy-substituted donors are reported, including a 4:1 salt with the meso stereoisomer of the dinuclear [Fe2(oxalate)5 ]4- anion in which both cation and anion have chiral components linked together by hydrogen bonding, and a semiconducting salt with triiodide.

Item Type: Journal article
Publication Title: Tetrahedron
Creators: Awheda, I., Krivickas, S.J., Yang, S., Martin, L., Guziak, M.A., Brooks, A.C., Pelletier, F., Le Kerneau, M., Day, P., Horton, P.N., Akutsu, H. and Wallis, J.D.
Publisher: Elsevier
Date: 2013
Volume: 69
Number: 41
ISSN: 0040-4020
Identifiers:
NumberType
10.1016/j.tet.2013.07.089DOI
Divisions: Schools > School of Science and Technology
Depositing User: EPrints Services
Date Added: 09 Oct 2015 10:13
Last Modified: 09 Jun 2017 13:22
URI: http://irep.ntu.ac.uk/id/eprint/9559

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