Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts

Awheda, I., Krivickas, S.J., Yang, S., Martin, L. ORCID: 0000-0002-5330-5700, Guziak, M.A., Brooks, A.C., Pelletier, F., Le Kerneau, M., Day, P., Horton, P.N., Akutsu, H. and Wallis, J.D. ORCID: 0000-0001-7259-8783, 2013. Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts. Tetrahedron, 69 (41), pp. 8738-8750. ISSN 0040-4020

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Abstract

The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT-TTF acetamides. Three charge transfer salts of enantiopure poly-hydroxy-substituted donors are reported, including a 4:1 salt with the meso stereoisomer of the dinuclear [Fe2(oxalate)5 ]4- anion in which both cation and anion have chiral components linked together by hydrogen bonding, and a semiconducting salt with triiodide.

Item Type: Journal article
Publication Title: Tetrahedron
Creators: Awheda, I., Krivickas, S.J., Yang, S., Martin, L., Guziak, M.A., Brooks, A.C., Pelletier, F., Le Kerneau, M., Day, P., Horton, P.N., Akutsu, H. and Wallis, J.D.
Publisher: Elsevier
Date: 2013
Volume: 69
Number: 41
ISSN: 0040-4020
Identifiers:
NumberType
10.1016/j.tet.2013.07.089DOI
Divisions: Schools > School of Science and Technology
Depositing User: EPrints Services
Date Added: 09 Oct 2015 10:13
Last Modified: 09 Jun 2017 13:22
URI: http://irep.ntu.ac.uk/id/eprint/9559

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