Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts

Awheda, I, Krivickas, SJ, Yang, S, Martin, L ORCID: https://orcid.org/0000-0002-5330-5700, Guziak, MA, Brooks, AC, Pelletier, F, Le Kerneau, M, Day, P, Horton, PN, Akutsu, H and Wallis, JD ORCID: https://orcid.org/0000-0001-7259-8783, 2013. Synthesis of new chiral organosulfur donors with hydrogen bonding functionality and their first charge transfer salts. Tetrahedron, 69 (41), pp. 8738-8750. ISSN 0040-4020

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Abstract

The syntheses of a range of enantiopure organosulfur donors with hydrogen bonding groups are described including TTF related materials with two, four, six and eight hydroxyl groups and multiple stereogenic centres and a pair of chiral N-substituted BEDT-TTF acetamides. Three charge transfer salts of enantiopure poly-hydroxy-substituted donors are reported, including a 4:1 salt with the meso stereoisomer of the dinuclear [Fe2(oxalate)5 ]4- anion in which both cation and anion have chiral components linked together by hydrogen bonding, and a semiconducting salt with triiodide.

Item Type:	Journal article
Publication Title:	Tetrahedron
Creators:	Awheda, I., Krivickas, S.J., Yang, S., Martin, L., Guziak, M.A., Brooks, A.C., Pelletier, F., Le Kerneau, M., Day, P., Horton, P.N., Akutsu, H. and Wallis, J.D.
Publisher:	Elsevier
Date:	2013
Volume:	69
Number:	41
ISSN:	0040-4020
Identifiers:	Number Type 10.1016/j.tet.2013.07.089 DOI
Divisions:	Schools > School of Science and Technology
Record created by:	EPrints Services
Date Added:	09 Oct 2015 10:13
Last Modified:	09 Jun 2017 13:22
URI:	https://irep.ntu.ac.uk/id/eprint/9559

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