Benjamin, SL ORCID: https://orcid.org/0000-0002-5038-1599 and Reid, G, 2015. Neutral organoantimony(III) and organobismuth(III) ligands as acceptors in transition metal complexes – role of substituents and co-ligands. Coordination Chemistry Reviews, 297, pp. 168-180. ISSN 0010-8545
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Abstract
This article reviews work up until mid-2014 on the synthesis and properties of transition metal complexes containing the heavier Group 15 Sb(III) and Bi(III) ligands, of general formula ER3 (E = Sb or Bi; R = alkyl, aryl etc, and may include a pendant donor group such as amine or ether) and ER(3-n)Xn (E = Sb or Bi; R is an organic substituent such as alkyl, aryl, etc.; X is an electronegative substituent such as halide; n = 0-3) in which these ligands function as a donor to a transition metal fragment, while simultaneously participating as an acceptor to another electronegative group such as an anionic or metal-coordinated halide, or an amine, ether, etc., leading to Sb/Bi centres bearing more than eight valence electrons ('hypervalent'). The Lewis acid properties of the halostibines and halobismuthines, ER(3-n)Xn, are also reviewed.
Item Type: | Journal article |
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Description: | Vols. 297-298 |
Publication Title: | Coordination Chemistry Reviews |
Creators: | Benjamin, S.L. and Reid, G. |
Publisher: | Elsevier |
Date: | 15 August 2015 |
Volume: | 297 |
ISSN: | 0010-8545 |
Identifiers: | Number Type 10.1016/j.ccr.2015.02.003 DOI |
Divisions: | Schools > School of Science and Technology |
Record created by: | EPrints Services |
Date Added: | 09 Oct 2015 10:45 |
Last Modified: | 09 Jun 2017 13:37 |
URI: | https://irep.ntu.ac.uk/id/eprint/17608 |
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