Zecchini, M, Lopez, JR, Allen, SW, Coles, SJ, Wilson, C, Akutsu, H, Martin, L ORCID: https://orcid.org/0000-0002-5330-5700 and Wallis, JD ORCID: https://orcid.org/0000-0001-7259-8783, 2015. Exo-methylene-BEDT-TTF and alkene-functionalised BEDT-TTF derivatives: synthesis and radical cation salts. RSC Advances, 5 (39), pp. 31104-31112. ISSN 2046-2069
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Abstract
Hydroxymethyl-BEDT-TTF is converted by tosylation and elimination into exo-methylene-BEDT-TTF whose exocyclic double bond leads to a small increase in the oxidation potential, and from which radical cation salts with perchlorate and triiodide have been prepared, the latter showing semiconductor properties. Allyloxymethyl- and allylthiomethyl-BEDT-TTF, the first BEDT-TTF derivatives with an alkene in the side chain, have been prepared, along with a 1 : 2 radical cation perchlorate salt of the former, an insulator which contains a donor dication.
Item Type: | Journal article |
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Publication Title: | RSC Advances |
Creators: | Zecchini, M., Lopez, J.R., Allen, S.W., Coles, S.J., Wilson, C., Akutsu, H., Martin, L. and Wallis, J.D. |
Publisher: | Royal Society of Chemistry |
Date: | 2015 |
Volume: | 5 |
Number: | 39 |
ISSN: | 2046-2069 |
Identifiers: | Number Type 10.1039/C5RA03921E DOI |
Rights: | © Royal Society of Chemistry 2015 |
Divisions: | Schools > School of Science and Technology |
Record created by: | EPrints Services |
Date Added: | 09 Oct 2015 11:16 |
Last Modified: | 09 Jun 2017 13:54 |
URI: | https://irep.ntu.ac.uk/id/eprint/25416 |
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