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Abedin, N, Hamed A Alshehri, A, Almughrbi, AMA, Moore, O, Alyza, S, Rusbridge, EK 
ORCID: https://orcid.org/0000-0001-8470-1039, Masood, N, Egbowon, BF, Hargreaves, AJ ORCID: https://orcid.org/0000-0001-9754-5477, Dafhnis-Calas, F and Fitzpatrick, AJ ORCID: https://orcid.org/0000-0001-9436-8129,
2020.
Expanding the family of tetrahalide iron complexes: synthesis, structure and biological applications.
Polyhedron: 114755.
ISSN 0277-5387
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Abstract
A neutral octahedral mononuclear iron(II) tetrabromide complex, [Fe(HaAmpy)2Br4], that consists of equatorial bromide and protonated aminopyrazinium axial ligands is successfully synthesised through redox chemistry and analysed using X-ray crystallography. The iron(II) oxidation state is balanced by the protonated pyrazinium nitrogen just outside the coordination sphere. The biological properties of this and two other related complexes are investigated using both Gram-negative and Gram-positive bacteria as well as methicillin resistant strains. They all exhibit some antimicrobial properties albeit at moderate to poor concentrations. However, the tetrahalide complexes analysed exhibit excellent anti-biofilm properties well below cytotoxic levels.
| Item Type: | Journal article |
|---|---|
| Publication Title: | Polyhedron |
| Creators: | Abedin, N., Hamed A Alshehri, A., Almughrbi, A.M.A., Moore, O., Alyza, S., Rusbridge, E.K., Masood, N., Egbowon, B.F., Hargreaves, A.J., Dafhnis-Calas, F. and Fitzpatrick, A.J. |
| Publisher: | Elsevier |
| Date: | 17 August 2020 |
| ISSN: | 0277-5387 |
| Identifiers: | Number Type 10.1016/j.poly.2020.114755 DOI S0277538720304125 Publisher Item Identifier 1353779 Other |
| Divisions: | Schools > School of Science and Technology |
| Record created by: | Linda Sullivan |
| Date Added: | 20 Aug 2020 07:51 |
| Last Modified: | 01 Feb 2022 15:42 |
| URI: | https://irep.ntu.ac.uk/id/eprint/40481 |
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