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Kimber, MC and Lee, DS 
ORCID: https://orcid.org/0000-0002-8288-1838,
2024.
The Kornblum DeLaMare rearrangement in natural product synthesis: 25 years of innovation.
Natural Product Reports.
ISSN 0265-0568
Abstract
Since its initial disclosure in 1951, the Kornblum DeLaMare rearrangement has proved an important synthetic transformation and has been widely adopted as a biomimetic step in natural product synthesis. Utilising the base catalysed decomposition of alkyl peroxides to yield a ketone and alcohol has found use in many syntheses as well as a key strategic step, including the unmasking of furans, as a biomimetic synthetic tool, and the use of the rearrangement to install oxygen enantioselectively. Since ca. 1998, its impact as a synthetic transformation has grown significantly, especially given the frequency of use in natural product syntheses, therefore this 25 year time period will be the focus of the review.
| Item Type: | Journal article |
|---|---|
| Publication Title: | Natural Product Reports |
| Creators: | Kimber, M.C. and Lee, D.S. |
| Publisher: | Royal Society of Chemistry (RSC) |
| Date: | 31 January 2024 |
| ISSN: | 0265-0568 |
| Identifiers: | Number Type 10.1039/d3np00058c DOI 1865568 Other |
| Divisions: | Schools > School of Science and Technology |
| Record created by: | Jeremy Silvester |
| Date Added: | 22 Feb 2024 09:44 |
| Last Modified: | 22 Feb 2024 09:44 |
| URI: | https://irep.ntu.ac.uk/id/eprint/50915 |
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