BEDT-TTF radical-cation salts with tris(oxalato)chromate and guest additives

Blundell, TJ, Ogar, JO ORCID: https://orcid.org/0000-0002-2115-2885, Brannan, MJ, Rusbridge, EK, Wallis, JD ORCID: https://orcid.org/0000-0001-7259-8783, Akutsu, H, Nakazawa, Y, Imajo, S and Martin, L ORCID: https://orcid.org/0000-0002-5330-5700, 2024. BEDT-TTF radical-cation salts with tris(oxalato)chromate and guest additives. RSC Advances, 14 (26), pp. 18444-18452. ISSN 2046-2069

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Abstract

The family of radical-cation salts β′′-(BEDT-TTF)4[(A)M3+(C2O4)3]·guest (M = Fe, Cr, Ga, Al, Co, Mn, Rh, Ru; A = K+, H3O+, NH4+) has produced superconductors, metals, semiconductors, and metal–insulators through introduction of different guest molecules into the structure. We present three new additions to the family β′′-(BEDT-TTF)4[(A)Cr(C2O4)3]·guest with the guest molecules toluene, phenol, or salicylaldehyde. These new guests are liquid or solid additives within the electrocrystallisation medium. All three salts show metallic behaviour from room temperature down to <10 K and do not show a superconducting transition.

Item Type:	Journal article
Publication Title:	RSC Advances
Creators:	Blundell, T.J., Ogar, J.O., Brannan, M.J., Rusbridge, E.K., Wallis, J.D., Akutsu, H., Nakazawa, Y., Imajo, S. and Martin, L.
Publisher:	Royal Society of Chemistry
Date:	10 June 2024
Volume:	14
Number:	26
ISSN:	2046-2069
Identifiers:	Number Type 10.1039/d4ra03425b DOI 1903232 Other
Rights:	This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Divisions:	Schools > School of Science and Technology
Record created by:	Jonathan Gallacher
Date Added:	13 Jun 2024 09:43
Last Modified:	13 Jun 2024 09:43
URI:	https://irep.ntu.ac.uk/id/eprint/51558

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