Chiral and racemic BINOL spiroborate anions and radical-cation salt with BEDT-TTF

Ogar, JO ORCID: https://orcid.org/0000-0002-2115-2885, Blundell, TJ, Usman, R, Vavrovič, M and Martin, L ORCID: https://orcid.org/0000-0002-5330-5700, 2024. Chiral and racemic BINOL spiroborate anions and radical-cation salt with BEDT-TTF. Polyhedron, 264: 117262. ISSN 0277-5387

Preview

Text 2262796_Martin.pdf - Published version Download (6MB) | Preview

Abstract

Sodium salts of the spiroborate anion bis[(1,1′-binaphthalene)-2,2′-diolato-O,O’]borate in enantiopure and racemic forms have been obtained through reaction of BORAX (sodium tetraborate hexahydrate) with the corresponding stereoisomers of BINOL [(1,1′-binaphthalene)-2,2′-diol]. Electrocrystallisation of these salts with BEDT-TTF produces single crystals of a 1:1 radical-cation salt, (BEDT-TTF){B[1,1′-bis(BINOL)]2}•THF, with the racemic spiroborate anion whilst no crystals were obtained with the enantiopure forms.

Item Type:	Journal article
Publication Title:	Polyhedron
Creators:	Ogar, J.O., Blundell, T.J., Usman, R., Vavrovič, M. and Martin, L.
Publisher:	Elsevier BV
Date:	1 December 2024
Volume:	264
ISSN:	0277-5387
Identifiers:	Number Type 10.1016/j.poly.2024.117262 DOI 2262796 Other
Rights:	© 2024 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/)
Divisions:	Schools > School of Science and Technology
Record created by:	Laura Borcherds
Date Added:	22 Jan 2025 11:40
Last Modified:	22 Jan 2025 11:40
URI:	https://irep.ntu.ac.uk/id/eprint/52903

Actions (login required)

Edit View

Statistics

Views

Downloads