Perylenediimide-based metal–organic frameworks: structural, electrochemical and spectroelectrochemical characterisation

Ogar, JO, Davies, ES, Almuhana, ARY, Griffin, SL, Addicoat, MA ORCID: https://orcid.org/0000-0002-5406-7927, Argent, SP and Champness, NR, 2025. Perylenediimide-based metal–organic frameworks: structural, electrochemical and spectroelectrochemical characterisation. Dalton Transactions. ISSN 1477-9226

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Abstract

The electrochemical and spectroelectrochemical behaviour of metal–organic frameworks (MOFs) using a perylene diimide (PDI) based ligand is reported. Through suitable functionalisation, a PDI-based ligand is made soluble, allowing successful synthesis of two MOFs in combination with cobalt dicarboxylate paddlewheel secondary building units. Spectroelectrochemical techniques are used to probe the electrochemical and optical behaviour of the MOFs demonstrating that the properties of the perylene diimide are maintained by the MOF, facilitating electrochromic behaviour.

Item Type:	Journal article
Publication Title:	Dalton Transactions
Creators:	Ogar, J.O., Davies, E.S., Almuhana, A.R.Y., Griffin, S.L., Addicoat, M.A., Argent, S.P. and Champness, N.R.
Publisher:	Royal Society of Chemistry (RSC)
Date:	2 October 2025
ISSN:	1477-9226
Identifiers:	Number Type 10.1039/d5dt02244d DOI 2516037 Other
Rights:	This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.
Divisions:	Schools > School of Science and Technology
Record created by:	Jeremy Silvester
Date Added:	24 Oct 2025 08:11
Last Modified:	24 Oct 2025 08:11
URI:	https://irep.ntu.ac.uk/id/eprint/54616

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