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Yang, S., Bristow, J.C., Addicoat, M.A. 
ORCID: 0000-0002-5406-7927 and Wallis, J.D. ORCID: 0000-0001-7259-8783,
2020.
One step conversion of 1,5-bis(dimethylamino)naphthalene to salts of “back to back” bis-acridine derivatives.
New Journal of Chemistry, 44 (23), pp. 9621-9625.
ISSN 1144-0546
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Abstract
Oxidation of 1,5-bis(dimethylamino)naphthalene with iodine leads directly to a bis(dimethyliminium) derivative of acridino[2,1,9,8-klmna]acridine, containing six fused six-membered rings, as a bis triiodide salt. The cation has a twisted structure due to the minimisation of peri interactions between each dimethyliminium group and a hydrogen atom. Use of TCNQ as oxidizing agent leads to the same dication as a tetrakis(TCNQ) salt, while use of TCNQ-F4 gave a related monocation which is dimethylated on a ring nitrogen atom.
| Item Type: | Journal article | ||||||
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| Publication Title: | New Journal of Chemistry | ||||||
| Creators: | Yang, S., Bristow, J.C., Addicoat, M.A. and Wallis, J.D. | ||||||
| Publisher: | Royal Society of Chemistry (RSC) | ||||||
| Date: | 21 June 2020 | ||||||
| Volume: | 44 | ||||||
| Number: | 23 | ||||||
| ISSN: | 1144-0546 | ||||||
| Identifiers: |
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| Divisions: | Schools > School of Science and Technology | ||||||
| Record created by: | Jill Tomkinson | ||||||
| Date Added: | 17 Jun 2020 12:31 | ||||||
| Last Modified: | 31 May 2021 15:04 | ||||||
| URI: | https://irep.ntu.ac.uk/id/eprint/40023 |
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