Yang, S, Bristow, JC, Addicoat, MA ORCID: https://orcid.org/0000-0002-5406-7927 and Wallis, JD ORCID: https://orcid.org/0000-0001-7259-8783, 2020. One step conversion of 1,5-bis(dimethylamino)naphthalene to salts of “back to back” bis-acridine derivatives. New Journal of Chemistry, 44 (23), pp. 9621-9625. ISSN 1144-0546
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Abstract
Oxidation of 1,5-bis(dimethylamino)naphthalene with iodine leads directly to a bis(dimethyliminium) derivative of acridino[2,1,9,8-klmna]acridine, containing six fused six-membered rings, as a bis triiodide salt. The cation has a twisted structure due to the minimisation of peri interactions between each dimethyliminium group and a hydrogen atom. Use of TCNQ as oxidizing agent leads to the same dication as a tetrakis(TCNQ) salt, while use of TCNQ-F4 gave a related monocation which is dimethylated on a ring nitrogen atom.
Item Type: | Journal article |
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Publication Title: | New Journal of Chemistry |
Creators: | Yang, S., Bristow, J.C., Addicoat, M.A. and Wallis, J.D. |
Publisher: | Royal Society of Chemistry (RSC) |
Date: | 21 June 2020 |
Volume: | 44 |
Number: | 23 |
ISSN: | 1144-0546 |
Identifiers: | Number Type 10.1039/d0nj00757a DOI 1317579 Other |
Divisions: | Schools > School of Science and Technology |
Record created by: | Jill Tomkinson |
Date Added: | 17 Jun 2020 12:31 |
Last Modified: | 31 May 2021 15:04 |
URI: | https://irep.ntu.ac.uk/id/eprint/40023 |
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